Lignin conversion into C4 dicarboxylic acids by catalytic wet peroxide oxidation using titanium silicalite-1
نویسندگان
چکیده
Lignin valorisation towards added-value products has become a relevant topic to consolidate future circular bioeconomy. In this context lignin oxidation C4 dicarboxylic acids (C4-DCA) by catalytic wet peroxide is emerging as value-added strategy, supported the extensive use of these building blocks in several industrial fields. work, lignins from different sources and processes (Indulin AT, Lignol, alkali E. globulus kraft lignins) were oxidised using H2O2 titanium silicalite-1 catalyst (TS-1) under operating conditions (temperature, pH, time, H2O2, TS-1 load). Indulin AT was leading highest succinic acid yield (11.3 wt%), enhanced its production four times over non-catalysed reaction. Malic also produced at high yields, especially for Lignol lignin. The other (E. kraft, but lower yields. remained stable used experimental conditions, showed potential be reused cycles without being deactivated. Overall, conversion C4-DCA can help guide pathway renewable chemicals production.
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ژورنال
عنوان ژورنال: Industrial Crops and Products
سال: 2021
ISSN: ['1872-633X', '0926-6690']
DOI: https://doi.org/10.1016/j.indcrop.2021.114155